CHM2041 Fall '97
Lecture 26

Oxides, Hydroxides, Hydrides,

and the

Strength of Acids and Bases

Consider Metal Hydroxides (soluble)

Clearly, these are electrolytes that produce stoichiometric quantities of OH- so they are all strong bases

Consider Non-Metal Hydroxides

These species are Acids because the weak bond is the O--H+ bond releasing H+ upon dissolution


Consider "organic" hydroxides

Don't forget 'Resonance'

Metal Oxides are STRONG Bases because they hydrate to form metal hydroxides

Non-metal Oxides may hydrate to form acids

Organic Oxides are not good acids or bases

Examples:

Ketones

Ethers

Epoxides


Non-Metal Hydrides (trends in acidity) HnX

Within a row (period) an increase in electronegativity of the element x increases the acidity of the acid

Ka: NH3 < H2O < HF

Within a column (group), the Acidity of a non-metal hydride varies inversely with the atomic/ionic radius of the non-metal element:

Ka: HF < HCl <= HBr


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